Product ID:7367, RHO TRON TE
MSDS Date:05/10/1988
FSC:6850
NIIN:00N027515
MSDS Number: BPLDX

RHO-CHEM CORP

425 ISIS AVE
INGELEWOOD, CA 90301-2009
US

Emergency Phone: 213-776-6233

Info Phone: 213-776-6233

Cage: 21414

RHO-CHEM CORP

6021 INGELEWOOD, CA 90301-2009 US

Telephone: 213-776-6233

Cage: 21414

UP & TIGHTLY CLSD.STOR TANKS SHLD BE ADEQ VENTED FOR

RTECS: 9999999ZZ

SHLD TERMINATE OUTDOORS. DO NOT STORE/HANDLE IN ALUM

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THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN EXPLO

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OPERATIONS ON/NEAR CNTNRS. STATIC ELEC MAY ACCUM &

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EQUIP. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN

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&/OR UV RADIA MAY CAUSE FORM OF CHLORIDES,

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PRIOR TO EATING, DRINKING/USING RESTROOM.

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QTYS MAY RSLT IN ASPIR PNEUM/SYS EFTS. PERS

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ETHYL ALCOHOL IS HAZ TO THEM JUST AS IS ALCOHOL FROM

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MAY FOLLOW INGEST OF SM AMTS OF ALCOHOL & HAVE ALSO

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MISUSE/OTHER MASSIVE EXPOS MAY RSLT IN DFCLT

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RANGES FROM LT HEAD TO UNCON & DEATH, & IS EVID BY

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BRTHG/CYANOSIS(BLUISH SKIN). IN SEV CASES DEATH MAY

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& RPTD EXPOS TO ING 2 HAVE RSLTD IN SUCH EFTS AS

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MUTAGENIC EFT HAS BEEN RPTD IN RATS.

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EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIM EFT IN

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CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAINING USES IN

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KEEP HEAD BELOW HIPS TO PVNT ASPIR OF LIQ

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OCCUR THRU LUNGS IF ASPIR & CAUSE SYS EFTS, DECISION

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SPECIAL BRTHG APPAR IS USED & OBSERVER IS

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ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 91.4%

OSHA PEL 1000 PPM;1250 STEL

ACGIH TLV: 1000 PPM;1250 STEL

(ORAL,RAT)13.7 G/KG.

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 8.6%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

PT. THERMAL DECOMP PRODS MAY INCL FLUORIDES,

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AS NA, K, CA, ALSO PWDRED AL, MG & ZN.

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AS PHOSGENE. CHLORIDES & FLUORIDES .

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LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY BE IRRIT TO
NOSE/THROAT/RESP TRACT. HIGH CONCS MAY RSLT IN CNS DEPRESS.
SKIN:LIQ IS IRRIT. PRLNG/RPTD CONT MAY CAUSE
REDDENING/ROUGHNESS/DRYNESS DUE TO REMOVAL OF NATRL OILS & MAY RSLT
IN DERM. CONT W/TENDER AREAS MAY RSLT IN TEMPORARY BURNING
SENSATION. EYES:LIQ IS SEV IRRIT & CAUSES (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TEMPORARY PAINFUL BURNING
SENSATION/TEARING/GEN INFLAMM/BLURRED VISION.HIGH VAP CONC MAY ALSO
CAUSE IRRIT.INGEST:LIQ IS POISONOUS.MAY CAUSE BLNDNESS/DEATH.LIQ IS
TOX & MAY BE HARMFUL.MAY PRDC E CNS DEPRESS.PROD MAY RSLT IN GI
IRRIT/NAUS/VOMIT/DIARR.ASPIR OF VOMITUS INTO LUNGS MUST BE AVOIDED
AS EVEN SM (ING 6)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE.

First Aid:EYE:IMMED FLUSH W/PLENTY OF H*2O FOR @ LST 15 MINS WHILE
HOLDING EYELIDS OPEN.GET MD.SKIN:REMOVE CONTAM CLTHG/SHOES & WIPE
EXCESS FROM SKIN.FLUSH W/H*2O.FOLLOW BY WASHING W/SOAP & H*2O.IF
IRRIT OCCURS , GET MD.DO NOT REUSE CLTHG UNTIL CLEANED.INHAL:REMOVE
VICTIM TO FRESH AIR & PROVIDE O*2 IF BRTHG IS DFCLT.GIVE ARTF RESP
IF NOT BRTHG.GET MD.INGEST:DO NOT INDUCE VOMIT.IF VOMIT OCCURS
SPONT, (ING 16)

Flash Point:NONE
Lower Limits:SEE ING 2
Upper Limits:SEE ING 2
Extinguishing Media:USE H*2O FOG, FOAM, DRY CHEM/CO*2. DO NOT USE
DIRECT STREAM OF H*2O. PROD WILL FLOAT & CAN BE REIGNITED ON SURF
OF H*2O.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT . WARNING. FLAMMABLE. CLEAR FIRE AREA
OF UNPROTECTED PERSONNEL.
Unusual Fire/Explosion Hazard:CNTNRS EXPOS TO INTENSE HEAT FROM FIRES
SHLD BE COOLED W/H*2O TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT IN
CNTNR RUPTURE. CNTNR AREAS EXPOS TO DIRECT (SUPDAT)

Spill Release Procedures:EVACUATE AREA, VENT & AVOID BRTHG VAPORS. DIKE
AREA TO CONTAIN SPILL. CLEAN UP AREA (WEAR PROT EQUIP) BY MOPPING
OR W/ABSORB MATL & PLACE IN CLSD CNTNRS FOR DISP. AVOID CONTAM OF
GROUND & SURF WATERS. DO NOT FLUSH TO SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:HANDLE W/REAS CARE & CAUT. AVOID BRTHG
VAPS. VAPS ARE HVR/AIR & WILL COLLECT IN LOW AREAS. DO NOT ENTER
AREAS WHERE VAPS ARE SUSPECTED UNLESS (ING 18)
Other Precautions:KEEP LIQ/VAP AWAY FROM HEAT/SPKS/FLAME.SURFS THAT ARE
SUFFICIENTLY HOT MAY IGNITE EVEN LIQ PROD IN ABSENCE OF
SPKS/FLAME.VAPS MAY ACCUM & TRAVEL TO IGNIT SOURCES DIST FROM HNDLG
SITE:FLASH-FIRE CAN RS LT.USE W/ADEQ VENT.CNTNRS, EVEN (ING 21)

Respiratory Protection:IF EXPOS MAY/DOES EXCEED OCCUP EXPOS LIMS USE A
NIOSH/MSHA APPRVD RESP TO PVNT OVEREXP. I/A/W 29 CFR 1910.134 USE
EITHER A NIOSH/MSHA APPRVD FULL-FACE, ATM SUPPLYING
RESP/AIR-PURIFYING RESP FOR ORGANI C VAPORS.
Ventilation:MAINTAIN WORKPLACE VAPOR CONCENTRATIONS @/BELOW
OCCUPATIONAL EXPOSURE LIMITS LISTED IN INGREDIENTS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:USE PROT CLTHG IMPERVIOUS TO MATL. SELECTION
OF SPEC ITEMS SUCH AS BOOTS, APRON/FULL-BODY SUIT WILL DEPEND ON
OPERATION.
Work Hygienic Practices:CONT LENSES SHLD NOT BE WORN. AVOID CONT W/SKIN
& BRTHG VAPS. DO NOT EAT/DRINK/SMOKE IN WORK AREA. WASH HANDS (ING
25)
Supplemental Safety and Health
EXPLO HAZ:FLAME CONT SHLD BE COOLED W/LG QTYS OF H*2O AS NEEDED TO PVNT
WEAKENING OF CNTNR STRUCT. VAPS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAM
ES, SPKS, HEATERS, SMOKING, ELEC MOTORS, STATIC DISCHARGE/OTHER
IGNIT SOURCES @ LOCATIONS DIST FROM MATL HNDLG (ING 3)

Boiling Pt:B.P. Text:112F,44C
Vapor Pres:8.64
Vapor Density:6.1
Spec Gravity:1.51
Evaporation Rate & Reference:1.4 (N-BUTYL ACETATE=1)
Solubility in Water:9% WT @ 25C
Appearance and Odor:CLEAR COLORLESS LIQUID; ETHER LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG OXIDIZING AGENTS, STRONG ALKALIES, STRONG MINERAL
ACIDS, BA, LI, MG & TI, ACTIVE METALS SUCH (ING 4)
Stability Condition to Avoid:AVOID HEAT & FLAME.
Hazardous Decomposition Products:CO & UNIDENTIFIED ORG CMPDS MAY BE
FORMED DURING COMBUST. HALOGENS, HALOGEN ACIDS & POSS CARBONYL
HALIDES, SUCH (ING 5)

Waste Disposal Methods:RECOVERED LIQS MAY BE SENT TO LICENSED
RECLAIMER/INCIN FACILITY. CONTAM MATL MUST BE DISP OF IN PERMITTED
HAZ WASTE MANAGEMENT FACILITY. CONSULT FED, STATE/LOC DISP AUTHS
FOR APPRVD PROCS. US EPA WAST E NUMBER:F002.

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particular situation.